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Enantioselective Protonation of the Lithium Transient Enolate of2-Methyltetralone with 2-Sulfinyl Alcohols

✍ Scribed by Jesús Gil; Mercedes Medio-Simon; Gisela Mancha; Gregorio Asensio


Book ID
102170375
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
103 KB
Volume
2005
Category
Article
ISSN
1434-193X

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Remarkable effect of lithium bromide in
✍ Gregorio Asensio; Pedro A. Aleman; Lius R. Domingo; Mercedes Medio-Simón 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 270 KB

The favourable effect of lithium bromide enhancing the facial enantioselectivity in the protonation of methyl tetralone enolate with ct-sulfinyl alcohols is described. Theoretical calculations allow to propose a model to explain the stereochemical course of the protonation reaction.