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Stereoselection Parameters and Theoretical Model in the Enantioselective Protonation of Enolates with α-Sulfinyl Alcohols

✍ Scribed by Asensio, Gregorio; Aleman, Pedro; Gil, Jesus; Domingo, Luis R.; Medio-Simon, Mercedes

Book ID
126814928
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
100 KB
Volume
63
Category
Article
ISSN
0022-3263

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Remarkable effect of lithium bromide in
Remarkable effect of lithium bromide in the enantioselective protonation with α-sulfinyl alcohols
✍ Gregorio Asensio; Pedro A. Aleman; Lius R. Domingo; Mercedes Medio-Simón 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 270 KB

The favourable effect of lithium bromide enhancing the facial enantioselectivity in the protonation of methyl tetralone enolate with ct-sulfinyl alcohols is described. Theoretical calculations allow to propose a model to explain the stereochemical course of the protonation reaction.