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Enantioselective Protonation of Silyl Enolates Catalyzed by a Binap×AgF Complex.

✍ Scribed by Akira Yanagisawa; Taichiro Touge; Takayoshi Arai

Publisher
John Wiley and Sons
Year
2005
Weight
22 KB
Volume
36
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enantioselective Al
ChemInform Abstract: Enantioselective Aldol Reaction of Tin Enolates with Aldehydes Catalyzed by BINAP×Silver(I) Complex.
✍ A. YANAGISAWA; Y. MATSUMOTO; H. NAKASHIMA; K. ASAKAWA; H. YAMAMOTO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 2 views

Enantioselective Aldol Reaction of Tin Enolates with Aldehydes Catalyzed by BINAP•Silver(I) Complex. -A new type of highly enantioselective aldol reactions of aldehydes with tributyltin enolates using the title complex as catalyst is described. Optimal conditions are established with THF as solvent