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Enantioselective Protonation of Silyl Enolates Catalyzed by a Binap⋅AgF Complex

✍ Scribed by Akira Yanagisawa; Taichiro Touge; Takayoshi Arai

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
102 KB
Volume
117
Category
Article
ISSN
0044-8249

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✍ A. YANAGISAWA; Y. MATSUMOTO; H. NAKASHIMA; K. ASAKAWA; H. YAMAMOTO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 2 views

Enantioselective Aldol Reaction of Tin Enolates with Aldehydes Catalyzed by BINAP•Silver(I) Complex. -A new type of highly enantioselective aldol reactions of aldehydes with tributyltin enolates using the title complex as catalyst is described. Optimal conditions are established with THF as solvent