ChemInform Abstract: Enantioselective Aldol Reaction of Tin Enolates with Aldehydes Catalyzed by BINAP×Silver(I) Complex.

✍ Scribed by A. YANAGISAWA; Y. MATSUMOTO; H. NAKASHIMA; K. ASAKAWA; H. YAMAMOTO

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 34 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199801030

✦ Synopsis

Enantioselective Aldol Reaction of Tin Enolates with Aldehydes Catalyzed by BINAP•Silver(I) Complex.

-A new type of highly enantioselective aldol reactions of aldehydes with tributyltin enolates using the title complex as catalyst is described. Optimal conditions are established with THF as solvent. The highest e.e. value is 95%. -(YANAGISAWA, A.;