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Enantioselective Organocatalytic One-Pot Amination/aza-Michael/Aldol Condensation Reaction Sequence: Synthesis of 3-Pyrrolines with a Quaternary Stereocenter

✍ Scribed by Alaric Desmarchelier; Dr. Vincent Coeffard; Dr. Xavier Moreau; Prof. Christine Greck

Book ID
115551646
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
379 KB
Volume
18
Category
Article
ISSN
0947-6539

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A Highly Enantioselective Catalytic Domi
A Highly Enantioselective Catalytic Domino Aza-Michael/Aldol Reaction: One-Pot Organocatalytic Asymmetric Synthesis of 1,2-Dihydroquinolidines
✍ Henrik Sundén; Ramon Rios; Ismail Ibrahem; Gui-Ling Zhao; Lars Eriksson; Armando 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 188 KB 👁 2 views

## Abstract The highly enantioselective organocatalytic domino aza‐Michael/aldol reaction is presented. The unprecedented, chiral amine‐catalyzed asymmetric domino reactions between 2‐aminobenzaldehydes and α,β‐unsaturated aldehydes proceed with excellent chemo‐ and enantioselectivity to give the c