Enantioselective lipase catalyzed esterification in organic medium for preparation of optically active secondary alcohols
โ Scribed by Doris Gerlach; Detlef Lutz; Boris Mey; Peter Schreier
- Book ID
- 112517773
- Publisher
- Springer
- Year
- 1989
- Tongue
- English
- Weight
- 238 KB
- Volume
- 189
- Category
- Article
- ISSN
- 0044-3026
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๐ SIMILAR VOLUMES
A convenient enzymatic method is presented for the preparation of optically pure 2-hydroxy-2-arylethanephosphonates. It is proved that 2-butyryloxy-2-arylethanephosphonates can be enantioselectively hydrolyzed in diisopropyl ether equilibrated with water to give both isomers in high yield and excell
A reaction temperature at S7OC produced an improvement of lipase's enantioselectivity for an esterification of a bulky substrate, such as 2-(2-methyl-or 4-trrr-butyl-phenoxy)propionic acid. in organic solvent with a suitable amount of water added. although the poor enantioselectivity was observed fo