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Enantioselective Hydrogenation with Solid Catalysts.

โœ Scribed by T. Mallat; A. Baiker


Publisher
John Wiley and Sons
Year
2010
Weight
22 KB
Volume
33
Category
Article
ISSN
0931-7597

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๐Ÿ“œ SIMILAR VOLUMES


Enantioselective hydrogenation of olefin
โœ Donna G. Blackmond; Andrew Lightfoot; Andreas Pfaltz; Thorsten Rosner; Patrick S ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 168 KB ๐Ÿ‘ 2 views

Cationic iridium complexes with chiral phosphinooxazoline ligands are efficient catalysts for the enantioselective hydrogenation of olefins. The complexes are readily prepared, air-stable, and easy to handle. In contrast to chiral rhodium- and ruthenium-phosphine catalysts, they do not require the p

Enantioselective Hydrogenation of Enones
โœ Caroline J. Scheuermann nรฉe Taylor; Christoph Jaekel ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 213 KB ๐Ÿ‘ 1 views

## Abstract Use of a typical rhodium precatalyst for hydroformylation results in the enantioselective hydrogenation of cyclic enones with up to 90% __ee__. Extensive screening of chiral ligands reveals the simple ligand Chiraphos as the best ligand, so far. The hydrogenation shows high chemoselecti