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Enantioselective Hydrogenation of Imines with Chiral (Phosphanodihydrooxazole)iridium Catalysts

✍ Scribed by Patrick Schnider; Guido Koch; Roger Prétôt; Guozhi Wang; Frank Michael Bohnen; Carl Krüger; Andreas Pfaltz

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Volume
3
Category
Article
ISSN
0947-6539

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Enantioselective hydrogenation of olefin
Enantioselective hydrogenation of olefins with phosphinooxazoline-iridium catalysts
✍ Donna G. Blackmond; Andrew Lightfoot; Andreas Pfaltz; Thorsten Rosner; Patrick S 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 168 KB 👁 2 views

Cationic iridium complexes with chiral phosphinooxazoline ligands are efficient catalysts for the enantioselective hydrogenation of olefins. The complexes are readily prepared, air-stable, and easy to handle. In contrast to chiral rhodium- and ruthenium-phosphine catalysts, they do not require the p