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ChemInform Abstract: Enantioselective Hydrogenation of Olefins with Iridium—Phosphanodihydrooxazole Catalysts.

✍ Scribed by Andrew Lightfoot; Patrick Schnider; Andreas Pfaltz

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
30
Category
Article
ISSN
0931-7597

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Enantioselective hydrogenation of olefin
Enantioselective hydrogenation of olefins with phosphinooxazoline-iridium catalysts
✍ Donna G. Blackmond; Andrew Lightfoot; Andreas Pfaltz; Thorsten Rosner; Patrick S 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 168 KB 👁 2 views

Cationic iridium complexes with chiral phosphinooxazoline ligands are efficient catalysts for the enantioselective hydrogenation of olefins. The complexes are readily prepared, air-stable, and easy to handle. In contrast to chiral rhodium- and ruthenium-phosphine catalysts, they do not require the p