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Enantioselective Hydrogenation of Olefins with Planar Chiral Iridium Ferrocenyloxazolinylphosphine Complexes.

โœ Scribed by Xinsheng Li; Qing Li; Xiaohua Wu; Yongguang Gao; Dongcheng Xu; Lichun Kong


Publisher
John Wiley and Sons
Year
2007
Weight
27 KB
Volume
38
Category
Article
ISSN
0931-7597

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Enantioselective hydrogenation of olefin
โœ Donna G. Blackmond; Andrew Lightfoot; Andreas Pfaltz; Thorsten Rosner; Patrick S ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 168 KB ๐Ÿ‘ 2 views

Cationic iridium complexes with chiral phosphinooxazoline ligands are efficient catalysts for the enantioselective hydrogenation of olefins. The complexes are readily prepared, air-stable, and easy to handle. In contrast to chiral rhodium- and ruthenium-phosphine catalysts, they do not require the p