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Synthesis of Iridium Complexes with Novel Planar Chiral Chelating Imidazolylidene Ligands.

✍ Scribed by Carsten Bolm; Thilo Focken; Gerhard Raabe

Publisher
John Wiley and Sons
Year
2003
Weight
153 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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## Abstract **Feel the pinch!** Planar–chiral, cationic, ruthenium–palladium complexes based on η^6^,η^1^‐coordinated ECE′ pincer ligands are synthesized as racemic mixtures by reacting ECE′–palladium complexes and [Ru(C~5~R~5~)(MeCN)~3~]^+^ arenophiles (R=H or Me). Chiral resolution of the cationi