𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Enantioselective hydrogenation of β-keto esters catalyzed by P-chiral bis(dialkylphosphino)ethanes-Ru(II)

✍ Scribed by Toru Yamano; Naohiro Taya; Mitsuru Kawada; Taisheng Huang; Tsuneo Imamoto

Book ID
104261045
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
182 KB
Volume
40
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Asymmetric hydrogenation of keto esters using a BisP*-RuBr_, catalyst is reported. High enantioselectivities up to 98% were achieved in the hydrogenation of [3-keto esters.

📜 SIMILAR VOLUMES

ChemInform Abstract: Enantioselective Hy
ChemInform Abstract: Enantioselective Hydrogenation of β-Keto Esters Catalyzed by P-Chiral Bis(dialkylphosphino)ethanes-Ru(II).
✍ Toru Yamano; Naohiro Taya; Mitsuru Kawada; Taisheng Huang; Tsuneo Imamoto 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Enantioselective Hydrogenation of β-Keto Esters Catalyzed by P-Chiral Bis(dialkylphosphino)ethanes-Ru(II). -The asymmetric hydrogenation of β-keto esters or related compounds to the corresponding secondary alcohols is readily achieved with a homogeneous Ru-catalyst based on a P-chiral bis(dialkylph

ChemInform Abstract: Enantioselective Hy
ChemInform Abstract: Enantioselective Hydrogenation of β-Keto Sulfones with Chiral Ru(II)-Catalysts: Synthesis of Enantiomerically Pure Butenolides and γ-Butyrolactones.
✍ P. Bertus; P. Phansavath; V. Ratovelomanana-Vidal; J.-P. Genet; A. R. Touati; T. 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 1 views

Enantioselective Hydrogenation of β-Keto Sulfones with Chiral Ru(II)-Catalysts: Synthesis of Enantiomerically Pure Butenolides and γ-Butyrolactones. -A highly enantioselective synthesis of chiral β-hydroxy sulfones (II), (VII) and (XII) is presented involving a novel ruthenium-catalyzed hydrogenati