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ChemInform Abstract: Enantioselective Hydrogenation of β-Keto Esters Catalyzed by P-Chiral Bis(dialkylphosphino)ethanes-Ru(II).

✍ Scribed by Toru Yamano; Naohiro Taya; Mitsuru Kawada; Taisheng Huang; Tsuneo Imamoto

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Enantioselective Hydrogenation of β-Keto Esters Catalyzed by P-Chiral Bis(dialkylphosphino)ethanes-Ru(II).

-The asymmetric hydrogenation of β-keto esters or related compounds to the corresponding secondary alcohols is readily achieved with a homogeneous Ru-catalyst based on a P-chiral bis(dialkylphosphino)ethane.

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ChemInform Abstract: Enantioselective Hy
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Enantioselective Hydrogenation of β-Keto Sulfones with Chiral Ru(II)-Catalysts: Synthesis of Enantiomerically Pure Butenolides and γ-Butyrolactones. -A highly enantioselective synthesis of chiral β-hydroxy sulfones (II), (VII) and (XII) is presented involving a novel ruthenium-catalyzed hydrogenati