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Enantioselective hydrogenation of alkenes and imines by a gold catalyst

✍ Scribed by González-Arellano, Camino; Corma, Avelino; Iglesias, Marta; Sánchez, Felix

Book ID: 119976721
Publisher: Royal Society of Chemistry
Year: 2005
Tongue: English
Weight: 267 KB
Volume: 27
Category: Article
ISSN: 1359-7345
DOI: 10.1039/B505271H

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## Abstract Use of a typical rhodium precatalyst for hydroformylation results in the enantioselective hydrogenation of cyclic enones with up to 90% __ee__. Extensive screening of chiral ligands reveals the simple ligand Chiraphos as the best ligand, so far. The hydrogenation shows high chemoselecti