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Enantioselective Hydrogenation of Alkenes and Imines by a Gold Catalyst.

✍ Scribed by Camino Gonzalez-Arellano; Avelino Corma; Marta Iglesias; Felix Sanchez


Book ID
101986449
Publisher
John Wiley and Sons
Year
2005
Weight
17 KB
Volume
36
Category
Article
ISSN
0931-7597

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Enantioselective Hydrogenation of Enones
✍ Caroline J. Scheuermann nΓ©e Taylor; Christoph Jaekel πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 213 KB πŸ‘ 1 views

## Abstract Use of a typical rhodium precatalyst for hydroformylation results in the enantioselective hydrogenation of cyclic enones with up to 90% __ee__. Extensive screening of chiral ligands reveals the simple ligand Chiraphos as the best ligand, so far. The hydrogenation shows high chemoselecti