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Highly Diastereoselective Hydrogenation of Imines by a Bimetallic Pd−Cu Heterogeneous Catalyst

✍ Scribed by Müslehiddinoğlu, Jale; Li, Jun; Tummala, Srinivas; Deshpande, Rajendra


Book ID
120170045
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
236 KB
Volume
14
Category
Article
ISSN
1083-6160

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In general, palladium ± carbon (Pd/C) catalyzed hydrogenation of epoxides affords the corresponding primary and secondary alcohols as a mixture. It has been found that the catalytic activity of a Pd/C ± ethylenediamine complex catalyst [Pd/C(en)] in the hydrogenolysis of epoxide functions is drastic