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Enantioselective Cyanosilylation of Ketones Catalyzed by Mn(salen)/Ph3PO.

โœ Scribed by Sung Soo Kim; Sang Hyuck Lee; Ju Myung Kwak


Publisher
John Wiley and Sons
Year
2006
Weight
26 KB
Volume
37
Category
Article
ISSN
0931-7597

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Enantioselective Cyanosilylation of Keto
โœ Do Hyun Ryu; E. J. Corey ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons โš– 25 KB

2005 Cyanation O 0273 Enantioselective Cyanosilylation of Ketones Catalyzed by a Chiral Oxazaborolidinium Ion. -Chiral oxazaborolidinium triflate (Ib) represents an efficient catalyst for the cyanosilylation of methyl ketones (II) and (V). The reaction proceeds with a reactive Ph2MePOTms(N=C:) inter