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Enantioselective Alkynylation of Ketones Catalyzed by Zn(Salen) Complexes

✍ Scribed by Pier Giorgio Cozzi

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 115 KB
Volume: 115
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200351230

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## Abstract magnified image Chiral macrocyclic tetra‐ and hexamine macrocycles derived from __trans__‐1,2‐diaminocyclohexane (DACH) in complexes with diethylzinc efficiently catalyze the asymmetric hydrosilylation of aryl alkyl ketones with enantiomeric excess of the product up to 89%. The cyclic