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Enantioselective cyanosilylation of aldehydes catalyzed by Mn(salen) complex/triphenyl phosphine oxide

โœ Scribed by Sung Soo Kim; Ju Myung Kwak; Soney C. George


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
115 KB
Volume
21
Category
Article
ISSN
0268-2605

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Asymmetric oxidation of sulfides catalyz
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## Abstract Catalytic properties of a series of chiral (pyrrolidine salen)Mn(III) complexes for asymmetric oxidation of aryl methyl sulfides were evaluated. Moderate activity, good chemical selectivity and low enantioselectivity were attained with iodosylbenzene as a terminal oxidant. Enantioselect