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Enantioselective Cyanosilylation of Ketones Catalyzed by a Chiral Oxazaborolidinium Ion

โœ Scribed by Ryu, Do Hyun; Corey, E. J.

Book ID
115314863
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
75 KB
Volume
127
Category
Article
ISSN
0002-7863

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Enantioselective Cyanosilylation of Keto
Enantioselective Cyanosilylation of Ketones Catalyzed by a Chiral Oxazaborolidinium Ion.
โœ Do Hyun Ryu; E. J. Corey ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons โš– 25 KB ๐Ÿ‘ 2 views

2005 Cyanation O 0273 Enantioselective Cyanosilylation of Ketones Catalyzed by a Chiral Oxazaborolidinium Ion. -Chiral oxazaborolidinium triflate (Ib) represents an efficient catalyst for the cyanosilylation of methyl ketones (II) and (V). The reaction proceeds with a reactive Ph2MePOTms(N=C:) inter