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Highly Enantioselective Cyanosilylation of Aldehydes Catalyzed by a Chiral Oxazaborolidinium Ion

โœ Scribed by Ryu, Do Hyun; Corey, E. J.

Book ID
115314862
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
40 KB
Volume
126
Category
Article
ISSN
0002-7863

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2005 Cyanation O 0273 Enantioselective Cyanosilylation of Ketones Catalyzed by a Chiral Oxazaborolidinium Ion. -Chiral oxazaborolidinium triflate (Ib) represents an efficient catalyst for the cyanosilylation of methyl ketones (II) and (V). The reaction proceeds with a reactive Ph2MePOTms(N=C:) inter