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Enantioselective Cyanosilylation of Ketones by a Catalytic Double-Activation Method Employing Chiral Lewis Acid and Achiral N -Oxide Catalysts

✍ Scribed by Chen, Fuxue; Feng, Xiaoming; Qin, Bo; Zhang, Guolin; Jiang, Yaozhong


Book ID
126471585
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
47 KB
Volume
5
Category
Article
ISSN
1523-7060

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Enantioselective Cyanosilylation of Keto
✍ Fu-Xue Chen; Hui Zhou; Xiaohua Liu; Bo Qin; Xiaoming Feng; Guolin Zhang; Yaozhon πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 223 KB πŸ‘ 2 views

## Abstract Double‐activation catalysis promises high catalytic efficiency in the enantioselective cyanosilylation of ketones through the combined use of a Lewis acid and a Lewis base. Catalyst systems composed of a chiral salen–Al complex and an N‐oxide have high catalytic turnovers (200 for aroma