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Highly Efficient Silylcyanation of Ketones by a Catalytic Double Activation Method Using Lewis Acid and N-Oxide Catalysts.

✍ Scribed by Fuxue Chen; Xiaoming Feng; Bo Qin; Guolin Zhang; Yaozhong Jiang


Publisher
John Wiley and Sons
Year
2003
Weight
119 KB
Volume
34
Category
Article
ISSN
0931-7597

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Enantioselective Cyanosilylation of Keto
✍ Fu-Xue Chen; Hui Zhou; Xiaohua Liu; Bo Qin; Xiaoming Feng; Guolin Zhang; Yaozhon πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 223 KB πŸ‘ 2 views

## Abstract Double‐activation catalysis promises high catalytic efficiency in the enantioselective cyanosilylation of ketones through the combined use of a Lewis acid and a Lewis base. Catalyst systems composed of a chiral salen–Al complex and an N‐oxide have high catalytic turnovers (200 for aroma