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Enantioselective Conjugate Addition of N , N -Dialkylhydrazones to α-Hydroxy Enones ‡

✍ Scribed by Monge, David; Martín-Zamora, Eloísa; Vázquez, Juan; Alcarazo, Manuel; Álvarez, Eleuterio; Fernández, Rosario; Lassaletta, José M.


Book ID
127095841
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
119 KB
Volume
9
Category
Article
ISSN
1523-7060

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Enantioselective conjugate radical addit
✍ Jin Young Lee; Sundae Kim; Sunggak Kim 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 491 KB

Enantioselective conjugate addition reactions of alkyl radicals to a 0 -phenylsulfonyl enones are described. A bis-oxazoline-zinc triflate complex proved to be an effective catalyst leading to high enantioselectivities and chemical yields.