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Enantioselective Conjugate Radical Addition to α‘-Hydroxy Enones

✍ Scribed by Lee, Sunggi; Lim, Chae Jo; Kim, Sunggak; Subramaniam, Rajesh; Zimmerman, Jake; Sibi, Mukund P.


Book ID
126000617
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
64 KB
Volume
8
Category
Article
ISSN
1523-7060

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Enantioselective conjugate radical addit
✍ Jin Young Lee; Sundae Kim; Sunggak Kim 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 491 KB

Enantioselective conjugate addition reactions of alkyl radicals to a 0 -phenylsulfonyl enones are described. A bis-oxazoline-zinc triflate complex proved to be an effective catalyst leading to high enantioselectivities and chemical yields.