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Enantioselective Radical Conjugate Addition to α′-Phosphoric Enones †

✍ Scribed by Lee, Sunggi; Kim, Sunggak


Book ID
125943071
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
127 KB
Volume
10
Category
Article
ISSN
1523-7060

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Enantioselective conjugate radical addit
✍ Jin Young Lee; Sundae Kim; Sunggak Kim 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 491 KB

Enantioselective conjugate addition reactions of alkyl radicals to a 0 -phenylsulfonyl enones are described. A bis-oxazoline-zinc triflate complex proved to be an effective catalyst leading to high enantioselectivities and chemical yields.