## Abstract For Abstract see ChemInform Abstract in Full Text.
Enantioselective conjugate addition of diethylzinc to enones using chiral β-aminoalcohol as chiral catalyst or ligand
✍ Scribed by Kenso Soai; Makoto Okudo; Masanori Okamoto
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 139 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Abstracti Conjugate addition of diethylzinc to chalcones is catalysed by complexes prepared in situ from Ni(acac), and cb-era-N,N-dialkyl-3-aminoisoborneols or (+)-ci.r-endo-N,N-dimethyl-3aminoborneol ((+)-DAB) (13b). The products are obtained with enantioselectivities up to 84 %. When scalemic (-)-
## Abstract The new chiral β‐aminoalcohols of indolinylmethanols (__1__) and their reduced derivatives (__2__) were synthesized from (__S__)‐indoline‐2‐carboxylic acid. Both (__R__) and (__S__) enantiomers of the optically active secondary alcohols have been successfully obtained in high enantiomer