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Enantioselective Allylic Etherification: Selective Coupling of Two Unactivated Alcohols

✍ Scribed by Markus Roggen; Prof. Dr. Erick M. Carreira

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
360 KB
Volume
50
Category
Article
ISSN
0044-8249

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Complex Allylation by the Direct Cross-C
Complex Allylation by the Direct Cross-Coupling of Imines with Unactivated Allylic Alcohols
✍ Masayuki Takahashi; Martin McLaughlin; Glenn C. Micalizio 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 408 KB 👁 2 views

## Abstract **Regioselective, stereoselective**: The convergent coupling of allylic alcohols with imines to deliver stereodefined homoallylic amines is described (see scheme). The process proceeds with net allylic transposition without the intermediacy of allylic organometallic reagents. Two stereo