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Enantioselective Additions of Diethylzinc and Diphenylzinc to Aldehydes Using 2-Dialkyl-aminomethyl-2‘-hydroxy- 1,1‘-binaphthyls

✍ Scribed by Ko, Dong-Hyun; Kim, Kyoung Hoon; Ha, Deok-Chan


Book ID
126101060
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
63 KB
Volume
4
Category
Article
ISSN
1523-7060

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Enantioselective addition of diethylzinc
✍ Hiroto Nakano; Noriyuki Kumagai; Hisao Matsuzaki; Chizuko Kabuto; Hiroshi Hongo 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 737 KB

Optically active 2-azanorbomylmethanols and 2-azanorbomylmethanethiol were prepared from ethyl (1 S,3S,4R)-2-[(R)-1-phenylethyl]-2-azabicyclo[2.2.1 ]hept-5 -ene-3-carboxylate and catalyzed the enantioselective addition of diethylzinc to aldehydes to give optically active secondary alcohols. ~) 1997