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Enantiopure β-Hydroxysulfoxide Derivatives as Novel Chiral Auxiliaries in Asymmetric Biaryl Suzuki Reactions

✍ Scribed by Broutin, Pierre-Emmanuel; Colobert, Françoise

Book ID
127191301
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
101 KB
Volume
5
Category
Article
ISSN
1523-7060

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An Asymmetric Biaryl Suzuki Cross-Coupli
An Asymmetric Biaryl Suzuki Cross-Coupling Reaction: Stereogenic Benzylic Carbinols as Chiral Auxiliaries
✍ Pierre-Emmanuel Broutin; Françoise Colobert 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 321 KB

## Abstract Asymmetric biaryl Suzuki coupling reactions were performed with various aryl‐ or naphthylhalide‐bearing enantiomerically pure benzylic alcohols and aryl‐ or naphthylboronic acids (or esters). The stereogenic benzylic alcohol was introduced by diastereoselective reduction of the arylhali