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An Asymmetric Biaryl Suzuki Cross-Coupling Reaction: Stereogenic Benzylic Carbinols as Chiral Auxiliaries.

✍ Scribed by Pierre-Emmanuel Broutin; Francoise Colobert

Book ID
101980024
Publisher
John Wiley and Sons
Year
2005
Weight
42 KB
Volume
36
Category
Article
ISSN
0931-7597

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An Asymmetric Biaryl Suzuki Cross-Coupli
An Asymmetric Biaryl Suzuki Cross-Coupling Reaction: Stereogenic Benzylic Carbinols as Chiral Auxiliaries
✍ Pierre-Emmanuel Broutin; Françoise Colobert 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 321 KB

## Abstract Asymmetric biaryl Suzuki coupling reactions were performed with various aryl‐ or naphthylhalide‐bearing enantiomerically pure benzylic alcohols and aryl‐ or naphthylboronic acids (or esters). The stereogenic benzylic alcohol was introduced by diastereoselective reduction of the arylhali