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Enantiopure β-Hydroxysulfoxide Derivatives as Novel Chiral Auxiliaries in Asymmetric Biaryl Suzuki Reactions.

✍ Scribed by Pierre-Emmanuel Broutin; Francoise Colobert

Book ID
101950369
Publisher
John Wiley and Sons
Year
2003
Weight
186 KB
Volume
34
Category
Article
ISSN
0931-7597

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An Asymmetric Biaryl Suzuki Cross-Coupli
An Asymmetric Biaryl Suzuki Cross-Coupling Reaction: Stereogenic Benzylic Carbinols as Chiral Auxiliaries
✍ Pierre-Emmanuel Broutin; Françoise Colobert 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 321 KB

## Abstract Asymmetric biaryl Suzuki coupling reactions were performed with various aryl‐ or naphthylhalide‐bearing enantiomerically pure benzylic alcohols and aryl‐ or naphthylboronic acids (or esters). The stereogenic benzylic alcohol was introduced by diastereoselective reduction of the arylhali