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Enantiopure 1-hydroxymethyl-2-dimethylaminomethylferrocene as efficient catalyst in the enantioselective addition of diethylzinc to aldehydes

✍ Scribed by Giovanni Nicolosi; Angela Patti; Raffaele Morrone; Mario Piattelli


Book ID
108036208
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
232 KB
Volume
5
Category
Article
ISSN
0957-4166

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Enantioselective addition of diethylzinc
✍ Hiroto Nakano; Noriyuki Kumagai; Hisao Matsuzaki; Chizuko Kabuto; Hiroshi Hongo πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 737 KB

Optically active 2-azanorbomylmethanols and 2-azanorbomylmethanethiol were prepared from ethyl (1 S,3S,4R)-2-[(R)-1-phenylethyl]-2-azabicyclo[2.2.1 ]hept-5 -ene-3-carboxylate and catalyzed the enantioselective addition of diethylzinc to aldehydes to give optically active secondary alcohols. ~) 1997