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Enantiomerically Pure α-Amino Acid Synthesis via Hydroboration−Suzuki Cross-Coupling

✍ Scribed by Collier, Philip N.; Campbell, Andrew D.; Patel, Ian; Raynham, Tony M.; Taylor, Richard J. K.

Book ID
111652001
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
196 KB
Volume
67
Category
Article
ISSN
0022-3263

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Protected allylglycine has been hydroborated and the intermediate organoborane employed in Suzuki coupling reactions with a number of ole®nic, aromatic and heteroaromatic bromides and iodides to produce a range of novel a-amino acids in good, unoptimised yields.