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Enantioconvergent Formal Synthesis of Brefeldin A via Sakai-Catalyzed Cyclization

✍ Scribed by Ducray, Pierre; Rousseau, Bernard; Mioskowski, Charles

Book ID
127253938
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
173 KB
Volume
64
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Enantioconvergent F
ChemInform Abstract: Enantioconvergent Formal Synthesis of Brefeldin A via Sakai-Catalyzed Cyclization.
✍ Pierre Ducray; Bernard Rousseau; Charles Mioskowski πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 2 views

Enantioconvergent Formal Synthesis of Brefeldin A via Sakai-Catalyzed Cyclization. -A formal total synthesis of the antitumor agent brefeldin A (XII) is presented by asymmetric synthesis of intermediate (XI). Key steps are the asymmetric Sakai cyclization of racemic pentenal (I) and the reductive a