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Enantio-differentiating hydrogenation of methyl acetoacetate over tartaric acid-NaBr-modified supported nickel catalyst prepared from nickel acetylacetonate

โœ Scribed by Tsutomu Osawa; Shinya Mita; Akiko Iwai; Osamu Takayasu; Hideto Hashiba; Seiichi Hashimoto; Tadao Harada; Ikuya Matsuura


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
402 KB
Volume
157
Category
Article
ISSN
1381-1169

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Studies of co-modifier and carboxylic ac
โœ Tsutomu Osawa; Yuki Nakagawa; Masashi Ando; Tadao Harada; Osamu Takayasu ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 185 KB

The effects of a co-modifier and carboxylic acid on the hydrogenation rate and the enantio-differentiating ability (e.d.a.) were studied for the hydrogenation of 2-octanone and methyl acetoacetate over a tartaric acid modified reduced nickel catalyst. For the hydrogenation of 2-octanone, tartaric ac