Enantio-differentiating hydrogenation of methyl acetoacetate over asymmetrically modified reduced nickel catalysts: The effects of the nickel sources on the enantio-differentiating ability
β Scribed by Tsutomu Osawa; Yuki Amaya; Tadao Harada; Osamu Takayasu
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 84 KB
- Volume
- 211
- Category
- Article
- ISSN
- 1381-1169
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The effects of a co-modifier and carboxylic acid on the hydrogenation rate and the enantio-differentiating ability (e.d.a.) were studied for the hydrogenation of 2-octanone and methyl acetoacetate over a tartaric acid modified reduced nickel catalyst. For the hydrogenation of 2-octanone, tartaric ac