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Enantio-differentiating hydrogenation of methyl acetoacetate over asymmetrically modified reduced nickel catalysts: The effects of the nickel sources on the enantio-differentiating ability

✍ Scribed by Tsutomu Osawa; Yuki Amaya; Tadao Harada; Osamu Takayasu


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
84 KB
Volume
211
Category
Article
ISSN
1381-1169

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The effects of a co-modifier and carboxylic acid on the hydrogenation rate and the enantio-differentiating ability (e.d.a.) were studied for the hydrogenation of 2-octanone and methyl acetoacetate over a tartaric acid modified reduced nickel catalyst. For the hydrogenation of 2-octanone, tartaric ac