𝔖 Bobbio Scriptorium
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Elucidation of the Structure of Epidermin, a Ribosomally Synthesized, Tetracyclic Heterodetic Polypeptide Antibiotic

✍ Scribed by Dr. Hermann Allgaier; Prof. Dr. Günther Jung; Priv.-Doz. Dr. Rolf G. Werner; Dr. Ursula Schneider; Prof. Dr. Hans Zähner

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
314 KB
Volume
24
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

✦ Synopsis

Addition of acrylamide to the electrolyte (0.5 M) leads to a decrease o f j l l m to 40% of the original value. The formation of polyacrylamide in the oxidation with chromic acid has been regarded as proof for the occurrence of radical

In the oxidation at the Ti/Cr20, anode, however, the possibility that layers of polymers on the electrodes leads to a decrease in current cannot be ruled out. Summarizing, it has been established that 2-propanol is oxidized to acetone at a Ti/Cr,03 anode via a mechanism analogous to that postulated by Westheimer for homogeneous oxidation with chromic acid. The lifetimes of the electrodes are still too short for use on an industrial scale, but we have already been able to achieve substantial improvements by using Sb20, as additional oxide component. [*]

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