High resolution mass spectrometry on time-of-flight (TOF) and ion trap (IT) mass spectrometers is used for the qualitative speciation of a heterodimetallic triple-stranded helicate [EuFe(L 1 ) 3 ](CIO 4 ) 5 and a toroidal complex [Ni 3 (L 2 ) 3 ](CIO 4 ) 6 (= circular single-stranded helicate) disso
Electrospray Ionization Mass Spectrometry in Supramolecular Chemistry: Characterization of Non-covalent Cyclodextrin Complexes
β Scribed by Lamcharfi, E.; Chuilon, S.; Kerbal, A.; Kunesch, G.; Libot, F.; Virelizier, H.
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 331 KB
- Volume
- 31
- Category
- Article
- ISSN
- 1076-5174
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β¦ Synopsis
A series of supramolecular complexes of various cycludextrins (CDs) was studied. Among the 13 CD complexes synthesized, 11 could be characterizied by electrospray ionization mass spectrometry. Different supramolecular entities, with host: guest ratios of 1 : 1 and 2: 1, were observed.
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