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Electrophilic Azidation for Stereoselective Synthesis of 2-Azido-2-deoxyaldono-1,5-lactones

✍ Scribed by Dileep Kumar, J. S.; Dupradeau, François-Yves; Strouse, M. Jane; Phelps, Michael E.; Toyokuni, Tatsushi

Book ID
126258536
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
58 KB
Volume
66
Category
Article
ISSN
0022-3263

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Synthesis of 5-(1-azido-2-haloethyl)arab
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✍ Rakesh Kumar; Leonard I. Wiebe; Edward E. Knaus 📂 Article 📅 1997 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 152 KB

## Abstract A novel class of 5‐(1‐azido‐2‐haloethyl)arabinouridines 4–6 was synthesized by the regiospecific addition of halogenoazides (XN~3~: X = C1, Br, I) to the vinyl substituent of 5‐vinylarabinouridine (7). The title 5‐(1‐azido‐2‐haloethyl)arabinouridines 4–6 were previously shown to exhibit