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Electrophilic and Nucleophilic Substitution of Allylic Mercurials

✍ Scribed by Sleezer, Paul D.; Winstein, S.; Young, W. G.

Book ID
121273461
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
296 KB
Volume
85
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Allylic coupling between electrophilic m
Allylic coupling between electrophilic molybdenum and nucleophilic iron allyl complexes
✍ S.R. Berryhill; J.G. Breitenbucher πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 271 KB

Allylic coupling between [CpMo(CO)(NO)(q3-allyl)]+ and CpFe(C0)2(q1-allyl) gives equal amounts of two stereoisomers of a 1,5-hexadiene in which the double bonds are complexed to different metals. Removal of the iron moiety yields a single diastereomer of a molybdenum -olefin complex. Investigation