Nucleophilic and electrophilic substitutions of difluoropropargyl bromides
β Scribed by Gerald B. Hammond
- Book ID
- 108170421
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 288 KB
- Volume
- 127
- Category
- Article
- ISSN
- 0022-1139
No coin nor oath required. For personal study only.
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## Abstract DFT computations on the mechanisms of nucleophilic substitutions on benzyl bromides were performed and the calculated activation parameters were compared with experimentally acquired data. In vacuo, the presence of electronβwithdrawing (eβw) groups on the benzyl bromides accelerated the