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Electrophilic additions to dienes. V. Orientation and kinetic secondary isotope effects in the addition of 2,4-dinitrobenzenesulfenyl chloride to phenylallene

โœ Scribed by Izawa, K.; Okuyama, T.; Fueno, T.

Book ID
126801541
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
279 KB
Volume
95
Category
Article
ISSN
0002-7863

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The k/ak isotope effect for addition of ArSCl to R-methylstyrene is small and unchanged by addition of LiClO ; k/'k is high and unchanged. k/Bk values are liigh and uncha:ged, while k/'k increases from For styrene and R-chlorostyrene -1.025 to -1.04. R-Methyl-