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Electrophilic addition to internal perfluoroolefins

✍ Scribed by M. A. Kurykin; I. N. Krotovich; Yu. N. Studnev; L. S. German; A. V. Fokin

Book ID
112446687
Publisher
Springer
Year
1982
Tongue
English
Weight
376 KB
Volume
31
Category
Article
ISSN
1573-9171

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Electrophilic additions to tetradehydrod
Electrophilic additions to tetradehydrodianthracene
✍ Herges, Rainer ;Neumann, Helfried πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 712 KB

## Abstract 5,12:6,11‐Di[1,2]benzenodibenzo[a,e]cyclooctene (tetrade‐hydrodianthracene, TDDA) (1) reacts with halogens to give transannular (__anti__) 4, 5 and ring‐opened (__syn__) products 6, 7. The product ratio shows a remarkable solvent dependence. Solvents of medium polarity favor __anti__ ad