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Electrophilic additions to (dimethylamino)allene

✍ Scribed by W. Klop; P. A. A. Klusener; L. Brandsma


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
281 KB
Volume
103
Category
Article
ISSN
0165-0513

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πŸ“œ SIMILAR VOLUMES


Electrophilic additions to tetradehydrod
✍ Herges, Rainer ;Neumann, Helfried πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 712 KB

## Abstract 5,12:6,11‐Di[1,2]benzenodibenzo[a,e]cyclooctene (tetrade‐hydrodianthracene, TDDA) (1) reacts with halogens to give transannular (__anti__) 4, 5 and ring‐opened (__syn__) products 6, 7. The product ratio shows a remarkable solvent dependence. Solvents of medium polarity favor __anti__ ad

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The kinetics and the products of the bromination of several cyclic allenes, from C 9 to C 13 (1 a Β± e), with tetrabutylammonium tribromide (TBAT) and Br 2 have been investigated in 1,2-dichloroethane (DCE) and methanol. The first product of the interaction between the allene and Br 2 is a 1:1 p comp