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Electronically Driven Structural Distortions in Lithium Intercalates of the n = 2 Ruddlesden—Popper-Type Host Y2Ti2O5S2: Synthesis, Structure, and Properties of LixY2Ti2O5S2 (0

✍ Scribed by Geoffrey Hyett; Oliver J. Rutt; Zoltan A. Gal; Sophie G. Denis; Michael A. Hayward; Simon J. Clarke


Publisher
John Wiley and Sons
Year
2004
Weight
62 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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The novel thioantimonate(III) [Fe(C 4 H 13 N 3 ) 2 ]Sb 6 S 10 • 0.5 H 2 O was synthesised under mild hydrothermal conditions by allowing elemental Fe, Sb, and S to react in a 50% diethylenetriamine (dien) solution. The compound crystallises in the monoclinic space group C2/c with a = 33.789(3), b =