Time-resolved infrared fluorescence observations of the Bf (4 'P,,,) spin-orbit excited state and the SO2 symmetric (v,) and antisymmetric (vl) stretching modes have been obtained following 532 nm laser photolysis of Br2/S02 and IBr/S02 mixtures. The total Bf quenching rate coefkient by SO\* was det
Electronic-to-vibrational energy transfer from Br (42P12 to HF
โ Scribed by Francis J. Wodarczyk; Philip B. Sackett
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 465 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0301-0104
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๐ SIMILAR VOLUMES
Collisional transfer of electronic energy from spin-orbit excited chlorine atoms, Cl\* [ ~P'(~P,,~) ] (E=882 cm-'), to vibrational energy in SOz has been observed by time-resolved infrared fluorescence from the fundamental SOI stretching levels. The rate constant ( k la) for Cl\* quenching by SO2 at
An optoacoustzc technique IS shown to gve accurate results for the extent of viirationai excltatton m electrornc-viirationai energy Qansfer. The system studied IS I(2P,,2)-Hz, and it IS shown that w&m experunental error the transfer 1s exctusively to the Ha@" = 2) viirational state. Unhke other meth
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