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Electronic Raman effect in the hexachloroiridate(IV) ion

✍ Scribed by R.J.H. Clark; P.C. Turtle

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 301 KB
Volume: 51
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80399-0

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✦ Synopsis

An electronic Raman spectrum has been observed in a resonance Raman study of the [ IrCle ] *-ion; the observed spectrum arises from transitions between the two spin-orbit components (U' per (U' ) state is split possibly by a Jahn-Teller effect into Kramers dou % % , Ei) of the *T, electronic ground state. The uplets (Ei, Eb), an 2 vibrational progressions are observed ased on each doublet.

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