A rigorous resonance Raman effect.was observed for the octahe.@ral IrCl~-' ,on.Anomalous'.~olJriutionu~~ found for all the observed R~mnn bands ;Ilclud~kg the totally symmetric u, band\_ '& ie[ation bctwcen the ;noma[y b the depolarization degxe and the Jahn-TeUef effect in the excited electronic st
Anomalous polarization in the resonance Raman effect of the octahedral hexabromoiridate(IV) ion
β Scribed by Hiro-o Hamaguchi; Takehiko Shimanouchi
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 478 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
A direct method for evaluation of resonance Raman spectra of cofljugated molecules is applied to the study of the anomalous polarization effect in metalIoporphyrins. The method provides a simpfe explanation for the inverse polarization effect. The quantitative nature of the method allows one to stud
## Abstract Anomalous polarization (Ο = 3/4 Λβ) has been observed in the resonance Raman spectra of some acetylenecumulene dehydro annulenes of a __D__~2__h__~ rectangular configuration. Because of no orbital degeneracy, the observed anomaly may certainly be explained by the vibronic coupling of th
An electronic Raman spectrum has been observed in a resonance Raman study of the [ IrCle ] \*-ion; the observed spectrum arises from transitions between the two spin-orbit components (U' per (U' ) state is split possibly by a Jahn-Teller effect into Kramers dou % % , Ei) of the \*T, electronic groun
Cucularl~ polvlzed radmtton III the long-sxbelength absorpuon region for o\>hemoglobm (=5600 A) produces mcreased scattermg present nenher with hnearly polarized radutlon nor wtth rzdntlon III the short-wa\e+length absorption regon (-4500-5000 .a) The result IS mcreased probabtity of melastlc hght s